Chip...
It's my understanding that the WS Earth undercoat is not really a paint. By that I mean it has no binders in it. It is water soluble...even after drying. WS's colors are meant to be a form of stain. They soak into their plaster products...rock castings, smooth-it road plaster, casting plaster, hydrocal, etc. They can be 'moved' or 'lightened', so to speak, by further applications of water.
That said, I would approach the brown boo-boo with the simplest of means first...pure water. Perhaps then a drop of detergent might help, as a next step.
Better yet....call the helpful folks at Woodland Scenics!! Ask to talk with a techie familiar with their colorants. Tell him/her of your situation. I'm sure they'll give you the best advice knowing the composition of their products.
It's been said before, and I can personally testify....the WS folks are very helpful and will talk you through any problem with their products.
After all, as the cliche' goes, "Get it from the horse's mouth!...Not the other end!"
Meanwhile, back at the ranch...
KD