I like most hobbyists an cost conceous, and though about doing a background roll or (several) but opted for doing some painting, using simple techniques
(you may well want to have something to practice on before you actually paint the walls)
On a clean(ish) wall I used a blue sky wall paint(latex) and a much lighter blue with a little gray ( dont remember the exact colors).
The Ceiling is low, and was already painted a darker blue.
Snap put a light chalk line where you want your horizon to be.
Working in ~3 foot sections (and 2 brushes/paint cans)
First paint on your darker sky color
While the Sky is still wet take your lighter color and paint (from bottom up) horizontal strokes.
Where the blues meets, blend them allowing variations in color mixes to transition from one color to the other (think about how looking out at the horizon looks where the blue sky above fades to white/gray/lt blue. It does Not need to be perfectly and evenly blended.. some places higher others lower. Use long wide even strokes when painting ....
Adding some clouds.
First off go outside on a day that is similar to how you want your clouds to look, and observer that the clouds overhead are large and singularly defined... as you look towards the horizon they get smaller and smaller till they blend into one
Application is pretty simple, use some of your light blue and white (do not mix super thoroughly, and have some 'gradient' where the bluish will be the bottom of the cloud and the white towards the top. Use a paper plate )
Using a Sea sponge dab into your paint where the top of the sponge is white, bottom blueish.
Apply in a dabbing and turning motion to where you want the clouds to go. Rotate dab rotate dab.... sea sponges can be easily cut if you need narrower shapes as you get closer to your horizon.
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Next trace in the Mountains, foreground ones first, then background filler.
Using some acrylic latex paints (greens (2 a darker and lighter) and a medium brown) paint in the background mountains them in with a mixture of brown and green (you want these to be rather dark.
Taking a can of grey spraypaint LIGHTLY spray over these background mountains to give a light haze (this adds depth)
If you want you can add multiple layers of background mountains each layer slightly larger than the last, and then hazing over them ... (I only did one)
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Last step the forground mountains:
Here you want your light and dark greens (maybe a touch of brown if its too light)
Squeeze out 2 generous lines of each the light and dark greens next to one and other on your palate(paper plate).
You will want a normal pantprushes for this. I used a 3" and a 1-12 inch brush.
Load the brush up with paint getting the light green towards one side of the brush and the dark green on the other.... its ok if they mis a little on the pallette ....
Now the Light side is where the sun is coming from and the dark is the shady side.
Apply the paint by dabbing the brush vertically (paying attention to light and dark sides of the brush) .
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Varying the brushes and brush pressure fill in your foreground mountains ... (all to taste)
-Pete Flaherty