Dallas the PHD electronic genius here John 
...............do you have a visual diagram ?
Edit- a major note here is the second coupler- ideally should be a LIONEL or MTH PS1 style coupler- rated for FULL track voltage!!!
A PS2/3 style electrocoupler is wound with a coil meant for LESS than track voltage and might fail or overheat if supplied FULL track voltage.
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Actually, being honest and reviewing this more, I'm not sure if the parallel load of both a factory PS3 coupler, and a relay coil in parallel is safe either. It just brings up a lot of limitations of the output of the PS3 board and the tiny SMD FET used. In other words, I'm sure the FET could fire a relay, maybe both couplers off the same relay output so that the board only sees the coil of the relay.
Going further, if you wanted to stick with original PS2/3 style couplers, then we also need that voltage source and ground- so more wires potentially in the tether system. I know PS3 diagrams could show us the connections to PV (positive voltage from the board) and pcb ground.
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I'm just saying, sure, I tried to help out and draw a diagram of what was being discussed. I'm not sure I can endorse this as being the best solution and the added inductive load and kickback of a relay coil in parallel to an existing coupler could push the limit and be as bad as 2 couplers.