I've been experimenting with these on a 3 rail TMCC equipped Weaver Baldwin VO1000 switcher. Out of the box the coupler is as Hot Water describes. It takes too much momentum to couple nicely. However, the coupler can be tamed a bit.
I haven't finished the experiment yet, but the first thing I did was to compare the profile with a Kadee coupler. I then took a Dremel and tried to match the profile of the Kadee.
All Atlas couplers have always had a centering spring that was too stiff. Many including myself use a Kadee centering spring to get better coupling action. The problem with the electro coupler is that the wires require a stiffer spring to compensate for the extra friction caused by the wires. I haven't replaced the Atlas centering spring yet, but the ability to use a softer spring would help.
What I have come up with so far is that after modifying the electro coupler's profile, coupling with an electro coupler engine and a Kadee equipped freight car works decently with the electro coupler closed and relying on the ability of the Kadee to easily go off center to make the joint. There is no problem with uncoupling. The biggest problem is coupling with the electro coupler open. I haven't done enough work to tell whether the effort needed to get the electro coupler to close can be overcome. The coupler can be triggered by both TMCC/Legacy and MTH's DCS. (I tried it with Proto2 DCS board.) I haven't worked with DCC yet.