Well, to further obfuscate the issue , here's the thing.
True-RMS AC voltage is relevant in O-gauge for incandescent lighting. In other words, if you have 14V AC RMS from a CW-80 (chopped-sine) or a Z-4000 (almost pure-sine) the lights should be equally bright.
HOWEVER.
If you are driving a vibrating/vibra-motor accessory (cattle car, rotating searching, wig-wag, etc.) 14V AC RMS from a chopped-sine source will generally produce more "action" than 14V AC RMS from pure or almost-pure sine source. This is because for the same RMS AC voltage, the peak or maximum voltage of a chopped sine source is larger than the peak or maximum voltage or a pure sine source. This larger peak voltage is, for all intents and purposes, what governs the electromechanical behavior of non-lighting accessories.
This also applies to solenoids as found in un-coupling UCS track sections. It's the peak voltage (not the RMS voltage) that for the most part determines the peak pulling force that determines whether the coupler releases.
This also applies to the heater resistor in most fan-driven smoke-units. For the same true-RMS AC voltage, a chopped-sine source will produce more heat than a pure sine source. This is because in fan-driven smoke units the AC voltage is converted to DC (to drive the DC fan motor) and hence these units generally power the heating resistor with DC voltage which tracks the peak AC voltage. IIRC there was even a Lionel video extolling the virtues of chopped sine transformers driving smoke units.
This also applies to DC illuminated accessories such as buildings which use LEDs (instead of filament bulbs). Again, if there is not some kind of DC voltage regulating circuit to level the playing field, the peak DC voltage following AC-to-DC conversion and smoothing will be higher from a chopped sine source than from a pure sine source of the same RMS AC voltage.
The bottom line, in my opinion, was suggested earlier. Go ahead and use the CW-80 and adjust (starting low) the voltage to simply confirm that the behavior of a particular accessory does indeed change with voltage. Now you know the accessory "works". If you want to use a meter to record the optimal voltage or voltage range, that's fine. Note what meter you used. Then, when you get your Z-4000 or ZW pure sine sources, simply keep in mind that it's not apples-to-apples. Though you should expect if Accessory A requires more voltage than Accessory B when using a CW-80...that the same will be true with the pure sine transformer.