There is quite a bit of difference.
On freight cars, when the brakes are applied on the cars and the automatic brake valve raises the brake pipe pressure (even just a couple of PSI) ALL of the cars release their brakes completely. So, when you stop a freight train, the brakes remain fully applied to the level that you applied them until the train stops.
On passenger cars, when the brakes are applied, the release of brakes can be graduated by making several brake pipe increases using the automatic brake valve. This allows smooth stops and smooth transitions from slowing the train for a curve or other reason.
Demonstrate what this does, in your automobile, by applying the brake and not easing up at all on the brake pedal until the car comes to a solid stop that makes your head bobble. Then repeat the stop, easing up on the brake pedal as you come to a smooth stop.
There's more to passenger train handling, of course, and finesse is very important for passenger comfort. Although the air brakes on passenger equipment are capable of very high performance, you have to resist hot rodding, because it is very uncomfortable for the passengers, and you might be able to decelerate at a rate that could cause a standing passenger to lose their balance, fall, and sustain an injury. Historically, most Engineers who were disqualified from passenger service either spilled the food in the diner or caused a passenger to fall. Because you are usually covering ground very fast on passenger, you have to always be thinking ahead about rapidly approaching curves, restrictions, stops, etc. You take all the turnouts at less than their permissible speed. You never, never get caught dreaming and go around a curve too fast. On freight, you also have to think ahead, but you usually have to begin reducing speed earlier because it takes more distance to slow or stop, due to the length and weight of the train.
And slack -- Hot Water is correct. There is definitely slack on passenger equipment and you could definitely give noticeable and uncomfortable slack action by mishandling the air brakes.