Matt, I have the same problem and it's even worse on 027 curves. Yes, as some have mentioned, running a heavier car with die-cast trucks directly behind the loco does help, but not every time.
And it's not just these locos but even some of the K-Line locos with the plastic centering "spring" can be so stiff that they do the same thing: Derail the lead car of a train that is going forward.
RMT uses if not the same, then an extremely similar design. I don't have a digital camera, and I didn't see the part on the Williams web site. So I'll do my best to describe the picture.
There is a "T" shaped pin that is in the center of the coupler mount to the truck. Where the "T" pin sets in the truck, the top of this is shaped something akin to a roller coaster... high in the back, and rolling downward on the sides.
On the bottom of the "T" pin and beneath the coupler arm, there is a spring with a washer and "C" clip. The spring pressure is good for keeping the coupler closed, but between the spring and the shape of the top of the mounting... well by hand swing the coupler to the left then to the right and you will feel that it doesn't move easily.
I tried using a softer spring, which helps in the left to right swing of the coupler arm, but isn't enough to keep the coupler closed.
First tip I can offer is when you are not running the trains, take the coupler and push it to one side (left or right) all the way until it "locks" in place, and leave it like that for a few days. Then do this again only to the other side. Sometimes this will help loose the spring pressure just enough to help with to and fro coupler arm swing.
If this fails to help, I have done one of two things. Using a Dremel (and yes you have to disassemble things) I grind down the slope of the top of the coupler mounting where the "T" sits on top... the area that resembles the roller coaster. I take the slope down and make it more gradual.
The other thing I have done is to replace the "T" pin with a screw and in place of the "C" clip on the bottom, I use either a stop nut or a stop clip. You'll lose the automatic centering of the coupler, but the derailments will completely disappear, even with a lighter lead car with plastic trucks.